Coordination Chemistry, States of Matter & Chemical Kinetics

Paper Code: 
24CCHY401
Credits: 
4
Contact Hours: 
60.00
Max. Marks: 
100.00
Objective: 

This course will enable the students to -

explain the trends in properties and reactivity of d and f block elements and acquaint with the basic concepts of coordination chemistry and nature of metal-ligand bonding in coordination compounds.

understand the properties and laws related to different states of matter and intermolecular interactions.

gain in-depth knowledge of experimental methods and theories of chemical kinetics.

 

Course Outcomes (COs):

Course

Learning Outcome

(at course level)

Learning and Teaching Strategies

Assessment Strategies

Course Code

Course

Title

 

24CCHY 401

Coordination Chemistry, States of Matter & Chemical Kinetics

(Theory)

 

 

CO37: Discuss and compare the properties of d and f block elements.

CO38: Predict IUPAC nomenclature, type of isomerism of coordination compounds. Describe the postulates and applications of VBT and CFT. Apply Jahn Teller theorem to explain square planar complexes.

CO39: Explain the kinetic theory of gases and Maxwell distribution of molecular velocities to describe the behaviour of gases.

CO40: Describe the characteristic properties of liquids and solids and apply Bragg’s equation for crystal structure determination.

CO41: Appraise the rules of kinetics to evaluate rate of reaction, order of reaction, rate constant and critically evaluate reaction rate theories.

CO42: Contribute effectively in course-specific interaction.

Approach in teaching:

Interactive lectures, tutorials, group discussions and e-learning.

 

Learning activities for the students:

Peer learning, e- learning, problem solving through tutorials and group discussions.

 

 

Written examinations,

assignments and quiz.

 

 

 

12.00
Unit I: 
Transition and Inner Transition Elements

Transition elements (3d series)-General group trends with special reference to electronic configuration, variable valency, colour, magnetic and catalytic properties, ability to form complexes and stability of various oxidation states (Latimer diagrams) for Mn, Fe and Cu.

Inner Transition Elements -Lanthanoids and actinoids: Electronic configurations, oxidation states, colour, magnetic properties, lanthanide and actinide contraction, separation of lanthanides (ion exchange method only).

 

14.00
Unit II: 
Coordination Chemistry and bonding

Review of Werner’s coordination theory, concept of effective atomic number (EAN concept).

Classification of ligands, IUPAC nomenclature of coordination compounds. Isomerism in coordination compounds, structural isomerism and its types, stereochemistry of complexes of 4 and 6 coordination number, salient features of valence bond theory (VBT), structure of octahedral, tetrahedral and square planar complexes of Cr, Fe, Co, Ni and Cu on the basis of VBT and its limitations.

Crystal Field Theory- Important postulates, crystal field splitting of d-orbitals in octahedral, tetrahedral and square planar complexes, factors affecting the magnitude of Δ0, calculation of crystal field stabilization energy (CFSE) , strong and weak ligands, spectrochemical series, distortion of octahedral complexes and Jahn Teller theorem. Use of CFSE values, number of unpaired electrons and high spin (HS) and low spin (LS) complexes, applications and limitations of CFT.

10.00
Unit III: 
Kinetic Theory of Gases

Postulates of kinetic theory of gases and derivation of the kinetic gas equation.

Deviation of real gases from ideal behaviour, compressibility factor, causes of deviation. Van der Waals equation of state for real gases. Boyle temperature (derivation not required). Law of corresponding states. Critical phenomena, critical constants and their calculation from van der Waals equation. Andrews isotherms of CO2.

Maxwell Boltzmann distribution laws of molecular velocities and molecular energies (graphic representation – derivation not required) and their importance. Temperature dependence of these distributions. Most probable, average and root mean square velocities. Collision cross section, collision number, collision frequency, collision diameter and mean free path of molecules. Viscosity of gases, effect of temperature and pressure on coefficient of viscosity (qualitative treatment only).

 

12.00
Unit IV: 
Liquids and Solids

Liquids: Characteristic properties of liquids: vapour pressure, surface tension, viscosity, refraction.  Surface tension and its determination using stalagmometer. Viscosity of a liquid and determination of coefficient of viscosity using Ostwald viscometer. Effect of temperature on surface tension and coefficient of viscosity of a liquid (qualitative treatment only). intermolecular forces

Solids : Forms of solids, unit cells, crystal systems, Bravais lattice types and identification of lattice planes. Laws of Crystallography- Law of constancy of interfacial angles, law of rational indices, symmetry elements, Miller indices. X-ray diffraction, Bragg’s law, a simple account of rotating crystal method and powder method, determination of crystal structure of NaCl, KCl and CsCl.
Defects in crystals, glasses and liquid crystals.

 

12.00
Unit V: 
Chemical Kinetics

The concept of reaction rates, effect of temperature, pressure, catalyst and other factors on reaction rates, order and molecularity of a reaction, Integrated rate equations for zero, first and second order reactions (both for equal and unequal concentrations of reactants), half–life of a reaction, general methods for determination of order of a reaction.

Concept of activation energy and its calculation from Arrhenius equation.

Theories of reaction rates: Collision theory and activated complex theory of bimolecular reactions, comparison of the two theories (qualitative treatment only).

 

Essential Readings: 
  1. Principles of Physical Chemistry, Forty Eighth Edition; B.R. Puri, L.R. Sharma, M. S. Pathania; Vishal Publishing Co., Jalandhar, India, 2020.
  2. Concise Inorganic Chemistry, Fifth Edition; J.D. Lee; Wiley India(P) Ltd, New Delhi, 2008.
  3. Principles of Inorganic Chemistry, Thirty Third Edition; B.R. Puri, L.R. Sharma, K.C. Kalia; Vishal Publishing Co., Delhi, 2020.

 

References: 
  1. Selected Topics in Inorganic Chemistry, G.D. Tuli, R.D. Madan, W.U. Malik; S Chand and Company Ltd, New Delhi, 2019.
  2. Inorganic Chemistry, Seventh International Edition; M. Weller, T. Overton, J. Rourke, F. Armstrong; Oxford University Press, New York, 2018.
  3. Atkin’s Physical Chemistry, Eighth Edition; P.W. Atkins, J. Paula; Oxford University Press, International Student Edition, 2017.
  4. Physical Chemistry, G.M. Barrow; International Students Edition; McGraw Hill, New Delhi, 1994.
  5. Physical Chemistry Through Problems, Second Edition; S.K. Dogra and S. Dogra; New Age International Pvt. Ltd, New Delhi, 2015.
  6. Text Book of Physical Chemistry, Third Edition, S. Glasstone, Mac Million India 1998.

 

e-Resources:

  1. https://chem.libretexts.org/Bookshelves/Inorganic_Chemistry/Inorganic_Coordination_Chemistry_(Landskron) (Unit 2)
  2. https://nios.ac.in/media/documents/313courseE/L23.pdf (Unit I)
  3. https://egyankosh.ac.in/handle/123456789/5248 (Unit I)
  4. https://nptel.ac.in/courses/104105033  (Unit II)
  5. https://www.unf.edu/~michael.lufaso/chem3610/Inorganic_Chapter20.pdf (Unit II)
  6. https://egyankosh.ac.in/handle/123456789/24790 (Unit III,IV)
  7. https://www.uou.ac.in/sites/default/files/slm/BSCCH-103.pdf, (see Block 2 for Unit III,IV) 
  8. https://archive.nptel.ac.in/courses/104/106/104106089/ (see week 10 & 11 for Unit V)
  9. https://www.uou.ac.in/sites/default/files/slm/BSCCH-103.pdf, (see Block 3 for Unit V)

 

 

Academic Year: