Inorganic Chemistry I

Paper Code: 
CHY-201
Credits: 
2
Contact Hours: 
30.00
Max. Marks: 
100.00
Objective: 

Course Objectives:    

This course will enable the students to –

  1. recall the general trends in the periodic table of elements.
  2. equip with the knowledge of gradation in properties of main group elements and theoretical concepts of different titrations of volumetric analysis like principle, applications and indicators used etc.

Course Outcomes (COs):

Course

Learning outcomes

(at course level)

Learning and teaching strategies

Assessment Strategies

Paper Code

Paper Title

CHY 201

Inorganic Chemistry I

(Theory)

 

The students will be able to –

 

CO20: describe the periodicity in properties, structures, applications and chemical reactivity of the s-block and p-block elements.

CO21: interpret and apply Frost and Latimer diagrams to predict chemical behavior and relative strengths of species as reductants and oxidants.

CO22: compare the properties, structure and bonding of different interhalogen compounds and xenon compounds.

CO23: describe the basic principles of volumetric analysis and demonstrate the related experiments.

 

Traditional chalk & board method with interactive lectures

 

Group discussions

 

Peer teaching and learning

 

Question preparation-Subjective type-Long answer &Short answer

 

Objective type-

Multiple choice questions,

 

One answer/two answer type questions

 

Assertion and reasoning

 

Class test

Semester end examinations

Quiz

Solving problems in tutorials

Assignments

Presentation

 

6.00
Unit I: 
s-Block Elements

General properties and comparative study of alkali and alkaline earth metals, diagonal relationship, anomalousbehaviour of Li and Be, salient features of hydrides and their classification (ionic, covalent and interstitial), solvation and complexation tendencies (crown ethers and cryptands).

7.00
Unit II: 
Periodicity in Properties of p-Block Elements

Prerequisite: General Properties of main group elements mentioned in semester I

Periodicity in properties of p-block elements with special reference to atomic and ionic radii, ionization energies, electron-affinity, electronegativity, allotropy, inert pair effect, catenation including diagonal relationship.

Some important compounds of p-block elements: Group 13 elements – Boron hydrides (diborane) and borazine; group 14 elements – Carbides and its classification, silicates (classification and structural aspect); group 15 elements – Structural aspects of oxides and oxy acids of N & P; group 16 elements – Structural aspects of oxy acids of S including peroxo acids.

6.00
Unit III: 
Halogens and Noble Gases

Unique position of Fluorine, basic nature of halogen, interhalogen compounds and polyhalides (only structural study).

Noble gases- Introduction, isolation, physical properties and uses, xenon compounds.

Unit IV: 
Oxidation and Reduction

Reduction potentials – Redox half reactions, concept of over potential, diagrammatic presentation of potential data (Latimer, Frost and Pourbaix diagrams), redox stability in water, reactions with water, disproportionation, oxidation by atmospheric oxygen, elements extracted by reduction – Ellingham diagrams.

5.00
Unit V: 
Basic Principles of Volumetric Analysis

Prerequisite: Basic principles of acid base titrations.

Simple theoretical background of following types of titrations:

Iodometric & iodimetric titrations: Basic principle, application in standardization of

iodine by CuSO4-hypo and H3AsO3.

Redox titrations: Standard potential, SHE, electrochemical series, emf calculations, internal & external indicators, applications in K2Cr2Ooxidation reaction.

Complexometric titrations: Types of EDTA titrations, masking and de-masking agents, metal ion indicator, application in estimation of total hardness of water.

Precipitation titrations: Basic principle, application in Volhard’s method.

References: 

  • Concise Inorganic Chemistry; Fifth Edition; J.D. Lee; Wiley India(P) Ltd, New Delhi, 2008.
  • Inorganic Chemistry; Seventh International Edition; M. Weller, T. Overton, J. Rourke, F. Armstrong; Oxford University Press, New York, 2018
  • Vogel’s Textbook of Quantitative Chemical Analysis; Sixth Edition; M. Thomas, B. Sivasankar, J. Mendham, R.C. Denney, J. D. Barnes; Pearson Education, New Delhi, 2009.
Academic Year: