Inorganic Chemistry VI

Paper Code: 
CHY - 611
Credits: 
3
Contact Hours: 
45.00
Max. Marks: 
100.00
9.00
Unit I: 
Symmetry and Group Theory
Symmetry elements and symmetry operations, definitions of group and subgroup, relation between orders of a finite group and its subgroup, conjugacy relation and classes, point group symmetry, Examples of H2O, NH3,CH4 etc.
 
10.00
Unit II: 
Radioactivity
Atomic Nucleus: mass defect. Nuclear forces: meson exchange theory. Nuclear models (elementary idea): Concept of nuclear quantum number, magic numbers. Natural radioactivity, Radioactive disintegration series, group displacement law, law of radioactive decay, half-life of radio elements. Nuclear Reactions; Artificial radioactivity, transmutation of elements, fission, fusion and spallation. Nuclear energy and power generation. Separation and uses of isotopes. Radio chemical methods: principles of determination of age of rocks and minerals, radio carbon dating, hazards of radiation and safety measures.
 
9.00
Unit III: 
Bioinorganic Chemistry
Elements of life: Essential, major and trace elements. Basic chemical reactions in the biological systems and the role of metal ions (specially Na+, K+, Mg2+ ,Ca2+, Fe3+/2+ ,Cu2+/+, and Zn2+). Metal ion transport across biological membrane, Na+-ion pump, ionophores. 
Biological functions of hemoglobin and myoglobin, cytochromes and ferredoxins, carbonate -bicarbonate buffering system and carbonic anhydrase. Biological nitrogen fixation, Photosynthesis: Photosystem-I and Photosystem-II. 
 
8.00
Unit IV: 
Supramolecular Chemistry-I
Molecular recognition: molecular receptors for different types of molecules including arisonic substrates, design and synthesis of coreceptor molecules and multiple recognition
 
9.00
Unit V: 
Solid State Reactions and Preparative Methods of Inorganic Solids
General principles, experimental procedures, co-precipitation as a precursor to solid state reactions, kinetics of solid state reactions. Preparative methods of inorganic solids (sol,gel   MOCVD processes) – crystallization of solutions, glasses, gels and melts, vapour phase transport methods, electrochemical reduction methods, preparation of thin films, growth of single crystals, high pressure and hydrothermal methods
 
References: 
  1. Solid State Chemistry and its Applications; A.R. West; John Wiley and Sons, Singapore,      2004. 
  2. Principles of Solid State, First Edition; H.V. Keer; New Age International Publishers, New Delhi, 2002.
  3. Advanced Inorganic Chemistry, Fifth Edition; F.A. Cotton and G. Wilkinson; John Wiley and Sons, USA, New York, 1988.
  4. Inorganic Chemistry; Third Edition; Gary L. Miessler and Donald A. Tarr; Pearson Education Inc. Singapore, 2007.
  5. Principles of Bioinorganic Chemistry; First Edition; S. J. Lippard, J.M. Berg; Panima Publishing Corporation, New Delhi, 2005.
 
  • Printer-friendly version
  • PDF version