History, Need and Goals. Green Chemistry and Sustainability and background of Green Chemistry.
Twelve Basic principles of Green Chemistry, Designing a Green Synthesis.
(i) Microwave assisted reactions
(ii) Ultrasound assisted reactions
(iii) Photochemical reactions using sunlight
(i) Heterogeneous Catalysis
(Zeolites, Silica, Alumina, Clay, Polymer (peracid and chromic acid), Cyclodextrin etc. supported catalysts)
(ii) Biocatalysis- Enzymatic oxidation, microbial oxidation and reduction
(iii) Phase-transfer Catalysis- application in N-alkylation/C-alkylation : Darzen reaction, wittig reaction, heterocyclic compounds, 3-alkyl coumarin, flavanones, oxiadation using H2O2, use of crownethers in esterification, aromatic substitution and ellimination reaction.
Oxidation reagents and catalysts; Biomimetic, multifunctional reagents; Combinatorial green chemistry; Proliferation of solventless reactions, Noncovalent derivatization.