IIS University

Admissions

It is a University which is committed to excellence and overall development of the student and one where talent is nurtured and honed in the best possible manner. Come, be a part of our never-ending journey of accomplishments and accolades.

Psychometric Counselling Tele-Counselling E-mail Counselling Subject Counselling International Admissions

Admissions

It is a University which is committed to excellence and overall development of the student and one where talent is nurtured and honed in the best possible manner. Come, be a part of our never-ending journey of accomplishments and accolades.

Read More

Placements

Excellent education not only imparts knowledge, but also paves the way for a promising and successful career. The Placement Cell at The IIS University has numerous success stories to narrate in this regard...

Read More

Life@IIS Univ

Life @ IISU is nothing less than a kaleidoscope of myriad hues; complete with vibrant events and memorable occasions to cherish for a lifetime.

Read More

Academics

Taking the age-old tradition of enlightenment through education forward, The IIS University - in its continuous pursuit of excellence - firmly believes that an institution’s academic profile determines its worth and value. Therefore, on offer are a wide variety of both conventional and contemporary programmes of study.

Read More

Research

To stimulate curiosity and cater to the global needs of a dynamic education, The IIS University - since inception - has been promoting and encouraging research-based experiential learning among all its students.

Read More

About Us

The IIS University, with its perfect amalgamation of innovation, inspiration and synergy, aims to be a model institution for students across disciplines and programmes.

Read More
OXYGEN CONTAINING FUNCTIONAL GROUPS | Chemistry

OXYGEN CONTAINING FUNCTIONAL GROUPS

Error message

  • Warning: ini_set(): Headers already sent. You cannot change the session module's ini settings at this time in drupal_environment_initialize() (line 691 of /home/iisunivac/public_html/includes/bootstrap.inc).
  • Warning: ini_set(): Headers already sent. You cannot change the session module's ini settings at this time in drupal_environment_initialize() (line 692 of /home/iisunivac/public_html/includes/bootstrap.inc).
  • Warning: ini_set(): Headers already sent. You cannot change the session module's ini settings at this time in drupal_environment_initialize() (line 693 of /home/iisunivac/public_html/includes/bootstrap.inc).
  • Warning: ini_set(): Headers already sent. You cannot change the session module's ini settings at this time in drupal_environment_initialize() (line 698 of /home/iisunivac/public_html/includes/bootstrap.inc).
  • Warning: ini_set(): Headers already sent. You cannot change the session module's ini settings at this time in drupal_environment_initialize() (line 702 of /home/iisunivac/public_html/includes/bootstrap.inc).
Paper Code: 
CHY 312
Credits: 
3
Contact Hours: 
45.00
Max. Marks: 
100.00
Objective: 

Course Objective(s):

This course will enable the students to –

  • Develop a perspective towards the mechanistic aspects of different oxygen containing functional groups

Course Outcomes (COs):

Course Outcomes

Teaching Learning strategies

Assessment

Strategies

On completion of this course, the students will be able to-

CO66: explain the synthesis and reactivity of various type of aliphatic alcohols (monohydric, dihydric and trihydric) and phenols 

CO67: describe the synthesis and reactivity of ethers and epoxides

CO68: predict the relative reactivity of different carbonyl compounds (saturated and unsaturated aldehydes and ketones) and their syntheses.

CO69: interpret the mechanism of prescribed name reactions

CO70: understand the acidity and reactivity of active methylene groups

CO71: outline the synthesis of carboxylic acids and its derivatives and compare the acidity of carboxylic acids, alcohols and phenols

CO72: analyse the factors affecting relative reactivity and stability of various carboxylic acids derivatives. 

  • Class lectures
  • Tutorials
  • Group discussions
  • Use of models
  • Assertion and reasoning
  • Technology enabled learning
  • Peer learning

 

  • Oral and written examinations
  • Problem solving exercises
  • Assignments
  • Quiz
  • Efficient delivery using seminar presentations
  • Group activity
  • Multiple choice questions
  • Short answer type questions
  • Assertion and reasoning

 

 

 

9.00
Unit I: 
Alcohols

Monohydric Alcohols- introduction, classification, methods of formation by reduction of aldehydes, ketones, carboxylic acid and esters, biological oxidation of ethanol, hydrogen bonding, acidic nature, comparison with thiols, effect of solvents and polarity, reactions of alcohols, distinction among primary, secondary, tertiary alcohols.
Dihydric alcohols- methods of preparation, chemical reactions of vicinal glycols, oxidative cleavage with [Pb(OAc)4] and HIO4, pinacol- pinacolone rearrangement.
Trihydric alcohols- introduction, methods of preparation, chemical reactions of glycerol

 

9.00
Unit II: 
Phenols, Ethers & Epoxides

Phenols- methods of preparation, acidity and factors affecting it, comparative acidic strength of alcohol and phenol, chemical reactions including important name reactions.
Ethers and Epoxides- preparation and reactions

 

9.00
Unit III: 
Carbonyl Compounds-I

Synthesis from acid chlorides, 1,3-dithianes and enamines, nitriles and carboxylic acids, mechanism of nucleophilic addition reaction to carbonyl group with particular emphasis on Benzoin, Perkin, aldol, Knoevenagel condensations, Reformatsky reaction and condensation with ammonia and its derivatives including reactions with primary & secondary amines, Mannich and Wittig reactions.

 

9.00
Unit IV: 
Carbonyl Compounds-II

Use of acetals as protecting groups, oxidation reactions- Baeyer- Villiger oxidation, Oppenauer oxidation, Cannizzaro reaction, reduction reactions- MPV reduction, Clemmensen reduction, Wolff-Kishner reduction, metal hydride reduction (LiAlH4, NaBH4 reductions)
α,β- unsaturated carbonyl compounds (cyclic & acyclic), Michael addition 1,2 v/s 1,4-addition
Active methylene compounds- acidity, keto-enol tautomerism, evidences in favour of keto-enol tautomerism, Claisen and Dieckmann condensation, preparation and synthetic applications of diethyl malonate & ethyl acetoacetate

 

9.00
Unit V: 
Carboxylic Acids & their Derivatives

Carboxylic acids- preparation, physical properties, acidity and reactions of monocarboxylic acids, dicarboxylic acids (succinic acid and phthalic acid), hydroxy acids (lactic acid, tartaric acid and citric acid) and unsaturated acids (maleic and fumaric acids)
Carboxylic acid derivatives- preparation and reactions of acid chlorides, anhydrides, esters and amides, mechanism of nucleophilic acyl substitution, relative reactivity and stability of carboxylic acid derivatives.

 

Essential Readings: 
  • Organic Chemistry, Sixth Edition; R. T. Morrison, R. N. Boyd; Pearson Education India, New Delhi, 2017.

 

References: 

SUGGESTED READINGS

  • Organic Chemistry, Second Edition; J. Clayden, N. Greeves, S. Warren; Oxford University Press, USA, 2014.
  • Organic Chemistry, Vol. I, Sixth Edition; I.L. Finar; Pearson Education, New Delhi, 2002.
  • Organic Chemistry, Fourth Edition (Indian Edition); G. Marc Loudon, J. Parise; WH Freeman, Oxford University Press, New Delhi, 2008.

e-RESOURCES

 

Academic Year: